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Star Piece

Star Piece is an item in the “Loot” category (Items). It costs ₽12000.

In-game descriptions

Ruby / Sapphire · EmeraldA red gem shard. It would sell for a very high price.
FireRed / LeafGreenA shard of a pretty gem that sparkles in a red color. It can be sold at a high price.
Diamond / Pearl · Platinum · HeartGold / SoulSilver · Black / White · Black 2 / White 2A shard of a pretty gem that sparkles in a red color. It can be sold at a high price to shops.
X / Y · Sun / Moon · Ultra Sun / Ultra MoonA small shard of a beautiful gem that demonstrates a distinctly red sparkle. It can be sold at a high price to shops.
Let’s Go, Pikachu! / Let’s Go, Eevee! · Sword / ShieldA small shard of a beautiful gem that gives off a distinctly red sparkle. It can be sold at a high price to shops.

Where to find it

PlaceGamesHowTile
Four IslandFRLGon the ground5, 6
Mt. Moon — B2FFRLGon the ground30, 26
Outcast IslandFRLGhidden16, 23
Resort GorgeousFRLGhidden40, 12
Route 108Eon the ground42, 4
Route 133RuSaon the ground8, 10
Route 133Eon the ground8, 10
Route 134Eon the ground22, 27
Treasure BeachFRLGhidden15, 29
UnderwaterRuSahidden12, 42
Underwater — Route 127Ehidden12, 42

Held by wild Pokémon (Generation 3)

Common: 50% · rare: 5% (60% / 20% with Compound Eyes in the lead), from SetWildMonHeldItem.

AlwaysJirachi
RareStaryu Starmie

Sources : PokeAPI (items, item_flavor_text, machines) · atlas · pokeemerald species_info.h