Rotom Catalog is an item in the “Gameplay” category (Key Items).
In-game descriptions
| Sword / Shield | A catalog of devices that Rotom like. Use the catalog to have Rotom hop in and out of the various devices listed within. |
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Where to find it
Not placed on the atlas maps (so far: Red/Blue and Generation 3).
Sources : PokeAPI (items, item_flavor_text, machines) · atlas · pokeemerald species_info.h